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For most spectrometers, systematic errors dominate by ~2 km/sec. Flexure, illumination differences between sky and lamp paths, asymmetric line profiles due to detector and spectrometer optics

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Spectrometer Design Guidelines | PDF | Angular

The guide defines key parameters, shows common spectrometer geometries, and cautions that numerical simulation is needed for hardware implementation.

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2.2: UV/Vis Instrumentation

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